Real Madrid - 100 points - La Liga 2011/12
Real Madrid ended Barcelona's three-year reign at the top of La Liga in emphatic style last season, as Jose Mourinho's side dethroned the Catalan club after reaching the 100-point milestone.
Exactly half of Real Madrid's points were won away from home, which represented another Primera Division record.
Barca's response has been nothing short of sensational, though, and after an explosive start to the 2012/13 campaign remain on course to better that tally this year, despite a recent dip in form.
Tito Vilanova's side are 13 points clear at the top of the table with 10 games remaining, and must pick up 27 out of a possible 30 points to better Real Madrid's total last season.